Mechanical property and corrosion resistance evaluation of AZ31 magnesium alloys by plasma electrolytic oxidation treatment: Effect of MoS2 particle addition

• Published in: Surface & coatings technology 2018-09, Vol.350, p.813-822
• Main Authors: Lou, Bih-Show, Lee, Jyh-Wei, Tseng, Chuan-Ming, Lin, Yi-Yuan, Yen, Chien-An
• Format: Article
• Language: English
• Subjects: AZ31 alloy; Corrosion resistance; MoS2 nanoparticle; Pin-on-disk wear; Plasma electrolytic oxidation; Scratch test
• ISSN: 0257-8972; 1879-3347
• DOI: 10.1016/j.surfcoat.2018.04.044

Magnesium alloys have been used in a wide range of lightweight applications in industries such as aerospace, automotive, and personal computing due to their high strength to weight ratio; however, high chemical reactivity, poor corrosion and wear resistance limit their widespread uses in many fields. The plasma electrolytic oxidation (PEO) process can produce a protective oxide layer on the magnesium alloy to improve the mechanical properties that limit more widespread application of magnesium alloys. In this work, molybdenum disulphide (MoS2) nanoparticles in concentrations ranging from 0 to 10 g/L were added into the PEO electrolyte. The aim of this study is to investigate the influence of incorporating MoS2 nanoparticles on the microstructure, phase, as well as short- and long-term corrosion resistance, and other mechanical properties of PEO grown oxides. While the MgAl2O4 phase was formed for all PEO grown oxide, the addition of MoS2 nanoparticles in the electrolyte reduced the formation of MgAl2O4 phase and enhanced the growth of MgO phase in the oxide coating. A higher hardness, 16.6 GPa, was obtained for the oxide layer grown with 10 g/L MoS2 nanoparticles added. The corrosion resistance, wear resistance, and adhesion of the PEO grown oxide layer were strongly influenced by the porosity defect, phase, and microstructure of the coating. It appears that the addition of 2.5 g/L MoS2 nanoparticle in electrolyte provided an oxide layer with the best short-term corrosion resistance, excellent adhesion, and the lowest wear rate; however, the addition of MoS2 nanoparticles to the PEO electrolyte was disadvantageous to the long-term anticorrosion performance of an oxide layer because of its reduced formation of MgAl2O4 phase. •Plasma electrolytic oxidation grows a MgAl2O4 based oxide layer on AZ31 Mg alloy.•Adding 2.5 g/L MoS2 grows a high hardness, good adhesion and anti-wear oxide layer.•Addition of MoS2 in electrolyte reduces the amount of MgAl2O4 phase in oxide layer.•The MgAl2O4-rich oxide layer can provide good long-term corrosion resistance.