Potentiostatic synthesis of polyaniline zinc and iron oxide composites for energy storage applications

• Published in: Synthetic metals 2025-02, Vol.310, p.117784, Article 117784
• Main Authors: Khan, Imran, Shah, Anwar ul Haq Ali, Bilal, Salma, Röse, Philipp
• Format: Article
• Language: English
• Subjects: Conductive polymer; Electrosynthesis; Energy storage; Functionalized polyaniline; Metal oxide nanoparticles
• ISSN: 0379-6779
• DOI: 10.1016/j.synthmet.2024.117784

This study introduces an efficient potentiostatic method to enhance the energy storage performance of polyaniline (PN) by synthesizing PN@ZnO (PNZ), PN@Fe2O3 (PNF), and PN@ZnFe2O4 (PNZF) hybrid electrodes with defined porous morphology. The precise selection and control of the working potential during electro-polymerization and metal oxide integration using the linear sweep voltammetry was key for synthesizing the polymer hybrid electrodes reproducible and with defined composition and structure. The PNZF electrode demonstrated the highest specific capacitances of 816 F g−1 and 791.3 F g−1 at a scan rate of 5 mV s−1 and 1.0 A g−1 current density, along with high power density and energy density of 1058.4 W kg−1 and 136.4 Wh kg−1, and with excellent stability retaining 90 % over 4000 cycles. We could attribute the excellent performance to a low charge transfer resistance of 25.0 Ω, a predominantly surface-controlled charge storage mechanism, and a porous morphology with uniform distribution of ZnFe2O4 particles in the polymer network, all resulting from the electrochemical synthesis method. Our study provides valuable and new insights into the structural, optical, and electrochemical properties of PN composites, particularly PNZF. •A facile electrochemical approach is used to synthesize polyaniline integrated metal oxides hybrid electrodes.•The in situ electrochemical incorporation of non-toxic metal oxides leads to porous polymer structures.•The highest specific capacitance of 791.3 F g−1 at a power density of 1058.4 W kg−1 was determined for polyaniline@ZnFe2O4.