Potential kinetic model for thermal decomposition of complex organic compounds: Significance of parameters and engineering application

•The potential model is useful for correlating isothermal and dynamic runs.•The significance of the kinetic parameters, especially E and n, is also discussed.•The potential model is compared with other correlation models. This paper analyzes the significance of the apparent activation energies and t...

Full description

Saved in:
Bibliographic Details
Published in:Thermochimica acta 2014-09, Vol.591, p.81-95
Main Author: Font, R.
Format: Article
Language:English
Subjects:
Activation energy
Kinetics
Reaction order
Thermal decomposition
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:•The potential model is useful for correlating isothermal and dynamic runs.•The significance of the kinetic parameters, especially E and n, is also discussed.•The potential model is compared with other correlation models. This paper analyzes the significance of the apparent activation energies and the reaction orders in potential kinetic models, their great interrelation and their influence in the design of reactors. The interrelation between the pre-exponential factor, the apparent activation energy and the reaction order is considered for a single reaction model and for a scheme of reactions. In addition, some simulated results of schemes of reactions were correlated satisfactorily by a single reaction model with surprising results concerning the activation energy and the reaction order. The potential model is compared with other correlation models proposed in literature. Finally, an analysis is presented on the use of the kinetic parameters for the design of industrial reactors.
ISSN:0040-6031
1872-762X
DOI:10.1016/j.tca.2014.07.017