O-Trimethylsilylenol ethers as versatile building blocks in a modular preparation of polyenic backbone

Versatility and synthetic potential of 1-(trimethylsilyloxy)-1,3-butadiene, 1-(trimethylsilyloxy)penta-1,3-diene, and their methyl substituted derivatives have been demonstrated in a modular synthetic methodology of stereodefined π-conjugated unsymmetrical, symmetrical two-dimensional, and octupolar...

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Bibliographic Details
Published in:Tetrahedron 2004-02, Vol.60 (8), p.1931-1939
Main Authors: Domagalska, Beata W, Syper, Ludwik, Wilk, Kazimiera A
Format: Article
Language:English
Subjects:
O-Trimethylsilyl enol ethers
Octupolar conjugated polyenes
Symmetrical conjugated polyenes
Unsymmetrical conjugated polyenes
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Summary:Versatility and synthetic potential of 1-(trimethylsilyloxy)-1,3-butadiene, 1-(trimethylsilyloxy)penta-1,3-diene, and their methyl substituted derivatives have been demonstrated in a modular synthetic methodology of stereodefined π-conjugated unsymmetrical, symmetrical two-dimensional, and octupolar polyenal structure. Graphic
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2003.12.008