Synthesis of sibiricinone A, sibiricinone B and leoheterin

Two labdenolides, sibiricinone A and sibericinone B, and a furo-labdane leoheterin have been synthesized from sclareol, for the first time, establishing in this manner the absolute configuration for these compounds. Three natural compounds sibiricinone A, sibircinone B and leoheterin have been synth...

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Bibliographic Details
Published in:Tetrahedron 2008-11, Vol.64 (48), p.10860-10866
Main Authors: Marcos, I.S., Castañeda, L., Basabe, P., Díez, D., Urones, J.G.
Format: Article
Language:English
Subjects:
Diterpenes
Labdanes
Leoheterin
Sclareol
Sibiricinone A
Sibiricinone B
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Summary:Two labdenolides, sibiricinone A and sibericinone B, and a furo-labdane leoheterin have been synthesized from sclareol, for the first time, establishing in this manner the absolute configuration for these compounds. Three natural compounds sibiricinone A, sibircinone B and leoheterin have been synthesized from sclareol. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2008.09.007