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Di-, tri-, and tetra-arylterephthalic acids as novel clathrate host compounds

Novel terephthalic acid host compounds having aromatic substituent 1– 4 have been prepared and their inclusion properties were investigated. These host compounds enclathrated several kinds of alcohols, ethers, ketones, amides, and sulfoxides. The X-ray structures of 1:1 2a/EtOH, 1:2 2b/DMF, 1:2 3/Me...

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Bibliographic Details
Published in:Tetrahedron 2009-03, Vol.65 (11), p.2318-2321
Main Authors: Tanaka, Koichi, Akiyoshi, Toshiyasu, Itoh, Hidehiro, Takahashi, Hiroki, Urbanczyk-Lipkowska, Zofia
Format: Article
Language:English
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Summary:Novel terephthalic acid host compounds having aromatic substituent 1– 4 have been prepared and their inclusion properties were investigated. These host compounds enclathrated several kinds of alcohols, ethers, ketones, amides, and sulfoxides. The X-ray structures of 1:1 2a/EtOH, 1:2 2b/DMF, 1:2 3/MeOH, and 1:1 4/EtOH complexes revealed complexation mode. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2009.01.031