A synthetic pathway to diquinane and angular triquinane systems via an iron carbonyl promoted tandem [6+2] ene type reaction

A model study is described on a new approach to the synthesis of diquinane and angular triquinane systems, via iron-promoted tandem [6+2] ene-type double cyclization followed by ozonolysis and intramolecular aldol reaction. [Display omitted]

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Bibliographic Details
Published in:Tetrahedron 2010-07, Vol.66 (27), p.4943-4946
Main Authors: Pearson, Anthony J., Kim, Eun Hoo, Sun, Huikai
Format: Article
Language:English
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Summary:A model study is described on a new approach to the synthesis of diquinane and angular triquinane systems, via iron-promoted tandem [6+2] ene-type double cyclization followed by ozonolysis and intramolecular aldol reaction. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2010.05.018