Synthesis and photophysical properties of α,ω-bis(terpyridine)oligothiophenes

Four novel fully π-conjugated α,ω-bis(terpyridine)oligothiophenes characterized by NMR, IR, and HR-mass spectroscopy are presented and their electronic absorption/emission and redox properties are described based on both experiments and theoretical calculations. These compounds can be potentially ut...

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Bibliographic Details
Published in:Tetrahedron 2011, Vol.67 (1), p.75-79
Main Authors: Svoboda, Jan, Štenclová, Pavla, Uhlík, Filip, Zedník, Jiří, Vohlídal, Jiří
Format: Article
Language:English
Subjects:
absorption
Chemistry
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Heterocyclic compounds with only one n hetero atom and condensed derivatives
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Materials science
Methods of nanofabrication
nuclear magnetic resonance spectroscopy
Organic chemistry
Physics
polymers
Preparations and properties
redox potential
Supramolecular and biochemical assembly
synthesis
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Summary:Four novel fully π-conjugated α,ω-bis(terpyridine)oligothiophenes characterized by NMR, IR, and HR-mass spectroscopy are presented and their electronic absorption/emission and redox properties are described based on both experiments and theoretical calculations. These compounds can be potentially utilized as building blocks for preparation of conjugated metallo-supramolecular polymers or dynamers and related functional materials. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2010.11.039