Fullerene containing norbornenes: synthesis and ring-opening metathesis polymerization

New norbornenes with the covalently bonded fullerene C60 have been prepared as monomers for ring-opening metathesis polymerization. Under the Grubbs catalyst these monomers smoothly enter homopolymerization as well as co-polymerization reactions with the parent ‘non-fullerene’ monomers. Homopolymers...

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Bibliographic Details
Published in:Tetrahedron 2014-10, Vol.70 (43), p.8040-8046
Main Authors: Miftakhov, Mansur S., Mikheev, Vladimir V., Torosyan, Seda A., Biglova, Yuliya N., Gimalova, Fanuza A., Menshov, Vladimir M., Mustafin, Akhat G.
Format: Article
Language:English
Subjects:
Co-polymers
Fullerene
Metathesis polymerization
Norbornenes
Polymers
Synthesis
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Summary:New norbornenes with the covalently bonded fullerene C60 have been prepared as monomers for ring-opening metathesis polymerization. Under the Grubbs catalyst these monomers smoothly enter homopolymerization as well as co-polymerization reactions with the parent ‘non-fullerene’ monomers. Homopolymers are insoluble in organic solvents whereas co-polymers obtained by 1:1 co-polymerization of the norbornenes with their ‘non-fullerene’ analogues are well soluble. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2014.08.039