Water as a hydrogen source in palladium-catalyzed reduction and reductive amination of nitroarenes mediated by diboronic acid

An unprecedented palladium-catalyzed chemoselective reduction and reductive amination of nitroarenes with water as a hydrogen source mediated by diboronic acid have been discovered. A series of aryl amines containing various reducible functional groups were obtained in good to excellent yields. [Dis...

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Bibliographic Details
Published in:Tetrahedron 2017-07, Vol.73 (27-28), p.3898-3904
Main Authors: Zhou, Yanmei, Zhou, Haifeng, Liu, Sensheng, Pi, Danwei, Shen, Guanshuo
Format: Article
Language:English
Subjects:
Diboronic acid
Hydrogen source
Nitroarenes
Reduction
Reductive amination
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Summary:An unprecedented palladium-catalyzed chemoselective reduction and reductive amination of nitroarenes with water as a hydrogen source mediated by diboronic acid have been discovered. A series of aryl amines containing various reducible functional groups were obtained in good to excellent yields. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2017.05.056