Utilization of IndPHOX-ligands in palladium-catalysed asymmetric allylic aminations

IndPHOX (indole phosphine oxazoline) ligands were utilized in palladium-catalysed asymmetric allylic amination with different N-nucleophiles. The reactions proceeded well and excellent enantioselectivities of up to 99% were achieved.

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Bibliographic Details
Published in:Tetrahedron: asymmetry 2011-03, Vol.22 (5), p.524-529
Main Authors: Wang, Yu, Vaismaa, Matti J.P., Hämäläinen, Antti M., Tois, Jan E., Franzén, Robert
Format: Article
Language:English
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Summary:IndPHOX (indole phosphine oxazoline) ligands were utilized in palladium-catalysed asymmetric allylic amination with different N-nucleophiles. The reactions proceeded well and excellent enantioselectivities of up to 99% were achieved.
ISSN:0957-4166
1362-511X
DOI:10.1016/j.tetasy.2011.03.004