Highly efficient chemical fixations of carbon dioxide and carbon disulfide by cycloaddition to aziridine under atmospheric pressure

Cycloaddition of aziridine with carbon dioxide was successfully catalyzed by alkali metal halide or tetraalkylammonium halide to give the corresponding 5-membered cyclic urethane, 1,3-oxazolidin-2-one, selectively. The reaction can be performed at ambient temperature under atmospheric pressure. Anal...

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Bibliographic Details
Published in:Tetrahedron letters 2003-10, Vol.44 (43), p.7889-7891
Main Authors: Sudo, Atsushi, Morioka, Yosuke, Koizumi, Eri, Sanda, Fumio, Endo, Takeshi
Format: Article
Language:English
Subjects:
atmospheric pressure
aziridine
carbon dioxide
carbon disulfide
cycloaddition
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Summary:Cycloaddition of aziridine with carbon dioxide was successfully catalyzed by alkali metal halide or tetraalkylammonium halide to give the corresponding 5-membered cyclic urethane, 1,3-oxazolidin-2-one, selectively. The reaction can be performed at ambient temperature under atmospheric pressure. Analoguous reaction of aziridine with carbon disulfide also successfully gave the corresponding 5-membered cyclic dithiourethane, 1,3-thioxazolidine-2-thione. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2003.09.011