The preparation of C-glycosyl amino acids—an examination of olefin cross-metathesis

[Display omitted] A study investigating the structural features directing olefin cross-metathesis to afford C-glycoamino acids was carried out. These results lead to an appreciation of the importance of proximal functionality to the relative reactivity of olefins in metathesis reactions providing a...

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Bibliographic Details
Published in:Tetrahedron letters 2005-07, Vol.46 (27), p.4677-4681
Main Authors: Schmidtmann, Frank W., Benedum, Tyler E., McGarvey, Glenn J.
Format: Article
Language:English
Subjects:
C-Glycosyl amino acids
Olefin cross-metathesis
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Summary:[Display omitted] A study investigating the structural features directing olefin cross-metathesis to afford C-glycoamino acids was carried out. These results lead to an appreciation of the importance of proximal functionality to the relative reactivity of olefins in metathesis reactions providing a variable that is useful to suppress undesirable self-metathesis.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2005.04.110