Free radical-promoted conjugate addition of activated bromo compounds using titanocene(III) chloride as the radical initiator

[Display omitted] Free radical-promoted conjugate addition of activated bromo compounds to α,β-unsaturated ketones and reactive α,β-unsaturated esters has been described using titanocene(III) chloride (Cp 2TiCl) as the radical initiator. Cp 2TiCl was prepared in situ from commercially available Cp 2...

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Bibliographic Details
Published in:Tetrahedron letters 2005-09, Vol.46 (36), p.6115-6117
Main Authors: Mandal, Samir Kumar, Jana, Samaraesh, Roy, Subhas Chandra
Format: Article
Language:English
Subjects:
Bromo compounds
Conjugate addition
Free radical
Titanocene(III) chloride
α,β-Unsaturated carbonyl compounds
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Summary:[Display omitted] Free radical-promoted conjugate addition of activated bromo compounds to α,β-unsaturated ketones and reactive α,β-unsaturated esters has been described using titanocene(III) chloride (Cp 2TiCl) as the radical initiator. Cp 2TiCl was prepared in situ from commercially available Cp 2TiCl 2 and activated zinc dust in THF.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2005.07.007