Evidence for proton transfer from carbon to chloride ion in solution

Evidence for proton transfer from carbon to chloride ion in solution has been obtained in the formation of hydroxamic acids from aldehydes and nitrosobenzenes in 99.9% acetonitrile. Unambiguous evidence for proton transfer from carbon to chloride ion in solution has been obtained for the first time,...

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Bibliographic Details
Published in:Tetrahedron letters 2006-01, Vol.47 (3), p.371-375
Main Authors: Pilepić, Viktor, Jakobušić, Cvijeta, Vikić-Topić, Dražen, Uršić, Stanko
Format: Article
Language:English
Subjects:
Chloride
Hydroxamic acids
Isotope effects
Kinetics
Proton transfer
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Summary:Evidence for proton transfer from carbon to chloride ion in solution has been obtained in the formation of hydroxamic acids from aldehydes and nitrosobenzenes in 99.9% acetonitrile. Unambiguous evidence for proton transfer from carbon to chloride ion in solution has been obtained for the first time, in the formation of hydroxamic acids from aldehydes and nitrosobenzenes in acetonitrile.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2005.11.005