A rapid acquisition of the bicyclo[3.3.1]nonan-9-one core present in garsubellin A and related phloroglucins

An exceptionally concise and stereoselective route to the prenylated bicyclo[3.3.1]nonan-9-one core present in garsubellin A and related phloroglucin natural products from the readily available precursor dimedone is delineated.

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Bibliographic Details
Published in:Tetrahedron letters 2006-01, Vol.47 (5), p.689-692
Main Authors: Mehta, Goverdhan, Bera, Mrinal K.
Format: Article
Language:English
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Summary:An exceptionally concise and stereoselective route to the prenylated bicyclo[3.3.1]nonan-9-one core present in garsubellin A and related phloroglucin natural products from the readily available precursor dimedone is delineated.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2005.11.120