A new class of self-assembly multinuclear Pt(II) coordination cages by a modular approach

The synthesis of self-assembly multinuclear Pt(II) cages is described in DMSO solutions of the participating components. The formation of three examples of a new class of self-assembly Pt(II) cage molecules of general formula [Pt m (ligand) n ](NO 3) 2 m is achieved from Pt(II) and ligands. The comp...

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Bibliographic Details
Published in:Tetrahedron letters 2006-04, Vol.47 (17), p.2867-2869
Main Authors: Chand, Dillip Kumar, Balaji, Ganapathy, Manivannan, Ramalingam, Athilakshmi, J.
Format: Article
Language:English
Subjects:
Cage compounds
Platinum
Proton NMR
Self-assembly
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Summary:The synthesis of self-assembly multinuclear Pt(II) cages is described in DMSO solutions of the participating components. The formation of three examples of a new class of self-assembly Pt(II) cage molecules of general formula [Pt m (ligand) n ](NO 3) 2 m is achieved from Pt(II) and ligands. The compounds are observed in solution state and confirmed from the similarity of their proton NMR behavior as compared with that of reported Pd(II) compounds of the formula [Pd m (ligand) n ](NO 3) 2 m .
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2006.02.132