An efficient deprotection of dithioacetals to carbonyls using Oxone–KBr in aqueous acetonitrile

A simple and efficient method has been developed for the chemoselective dethioacetalization of dithioacetals to aldehydes and ketones using Oxone–KBr in aqueous acetonitrile at room temperature. A simple and efficient method has been developed for the chemoselective dethioacetalization of dithioacet...

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Bibliographic Details
Published in:Tetrahedron letters 2006-11, Vol.47 (48), p.8559-8561
Main Authors: Desai, U.V., Pore, D.M., Tamhankar, B.V., Jadhav, S.A., Wadgaonkar, P.P.
Format: Article
Language:English
Subjects:
Deprotection
Dethioacetalization
Oxone
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Summary:A simple and efficient method has been developed for the chemoselective dethioacetalization of dithioacetals to aldehydes and ketones using Oxone–KBr in aqueous acetonitrile at room temperature. A simple and efficient method has been developed for the chemoselective dethioacetalization of dithioacetals to aldehydes and ketones using Oxone–KBr in aqueous acetonitrile at room temperature.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2006.09.138