Iodine-catalyzed allylation of 1,3-dicarbonyl compounds with allylic alcohols at room temperature

A highly efficient iodine-catalyzed allylation of 1,3-dicarbonyl compounds with a wide variety of allylic alcohols has been developed. The reaction is operationally straightforward and proceeds under very mild conditions at room temperature in good to excellent yields (up to 99%) and regioselectivit...

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Bibliographic Details
Published in:Tetrahedron letters 2008, Vol.49 (1), p.122-126
Main Authors: Rao, Weidong, Tay, Adeline Hui Ling, Goh, Pei Jing, Choy, Jessica Mun Ling, Ke, Justin Kaijie, Chan, Philip Wai Hong
Format: Article
Language:English
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Summary:A highly efficient iodine-catalyzed allylation of 1,3-dicarbonyl compounds with a wide variety of allylic alcohols has been developed. The reaction is operationally straightforward and proceeds under very mild conditions at room temperature in good to excellent yields (up to 99%) and regioselectivity.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2007.11.005