Total synthesis of the marine pyrroloiminoquinone alkaloid tsitsikammamine A

A concise route to the marine pyrroloiminoquinone alkaloid tsitsikammamine A and a regioisomer was developed. The synthesis was based on a Michael reaction between the indole dione 6 and 2′-amino-1-(4-methoxyphenyl)ethanol.

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Bibliographic Details
Published in:Tetrahedron letters 2009-03, Vol.50 (10), p.1128-1130
Main Authors: Rives, Arnaud, Delaine, Tamara, Legentil, Laurent, Delfourne, Evelyne
Format: Article
Language:English
Subjects:
Marine alkaloid
Pyrroloiminoquinone
Synthesis
Tsitsikammamine
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Description
Summary:A concise route to the marine pyrroloiminoquinone alkaloid tsitsikammamine A and a regioisomer was developed. The synthesis was based on a Michael reaction between the indole dione 6 and 2′-amino-1-(4-methoxyphenyl)ethanol.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2008.12.078