Hetero-Diels–Alder reaction of [60]fullerene with nitrosoalkene

A new type of stable C 60-fused dihydrooxazine derivatives was successfully prepared through the hetero-Diels–Alder reaction of C 60 with nitrosoalkenes generated in situ from the corresponding α-bromooxime by treatment with Na 2CO 3. A new type of stable C 60-fused dihydrooxazine derivatives was su...

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Bibliographic Details
Published in:Tetrahedron letters 2009-12, Vol.50 (52), p.7337-7339
Main Authors: Yang, Hai-tao, Ruan, Xiao-Jiao, Miao, Chun-bao, Xi, Hai-tao, Jiang, Yan, Meng, Qi, Sun, Xiao-qiang
Format: Article
Language:English
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Summary:A new type of stable C 60-fused dihydrooxazine derivatives was successfully prepared through the hetero-Diels–Alder reaction of C 60 with nitrosoalkenes generated in situ from the corresponding α-bromooxime by treatment with Na 2CO 3. A new type of stable C 60-fused dihydrooxazine derivatives was successfully prepared by the hetero-Diels–Alder reaction of C 60 with nitrosoalkene generated in situ by extrusion of HBr from the corresponding α-bromooxime.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2009.10.060