Rhodium(II) catalyzed cyclopropanation/cycloaddition reactions of the bis(diazo)piperidin-2-one system

[Display omitted] Bis(diazo)piperidin-2-ones that are devoid of a donor substituent in the 4-position undergo a one-pot cyclopropanation/cascade dipole formation/cycloaddition reaction to produce novel azapolycycles.

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Bibliographic Details
Published in:Tetrahedron letters 2015-06, Vol.56 (23), p.3127-3129
Main Authors: Bonderoff, Sara A., Padwa, Albert
Format: Article
Language:English
Subjects:
Bis(diazo)indolin-2-one
Carbenoid
Catalysis
Cyclopropanation
Dipolar cycloaddition
Rhodium(II)
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Description
Summary:[Display omitted] Bis(diazo)piperidin-2-ones that are devoid of a donor substituent in the 4-position undergo a one-pot cyclopropanation/cascade dipole formation/cycloaddition reaction to produce novel azapolycycles.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2014.12.020