Radical N-arylation/alkylation of sulfoximines

[Display omitted] •A copper-catalyzed N-arylation/alkylation of sulfoximines was developed.•Acyl peroxides served as aryl/alkyl sources.•Mechanistic studies suggest radical pathway is involved in the procedure. A novel copper-catalyzed N-arylation/alkylation of sulfoximines with acyl peroxides as ar...

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Bibliographic Details
Published in:Tetrahedron letters 2016-06, Vol.57 (22), p.2372-2374
Main Authors: Zhu, Hui, Teng, Fan, Pan, Changduo, Cheng, Jiang, Yu, Jin-Tao
Format: Article
Language:English
Subjects:
Acyl peroxide
Arylation
Copper
Radical pathway
Sulfoximine
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Summary:[Display omitted] •A copper-catalyzed N-arylation/alkylation of sulfoximines was developed.•Acyl peroxides served as aryl/alkyl sources.•Mechanistic studies suggest radical pathway is involved in the procedure. A novel copper-catalyzed N-arylation/alkylation of sulfoximines with acyl peroxides as aryl/alkyl source was developed. This approach undergoes a radical pathway, representing an alternative complement to construct N-arylated/alkylated sulfoximines.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2016.04.042