N-phosphorylation of pyrroles: An intramolecular migration reaction

[Display omitted] •Migration of phosphonate group.•Synthesis of N-phosphorylated pyrroles.•An intramolecular migration of a phosphonate diester group. A new synthetic method is reported for the N-phosphorylation of pyrroles via intramolecular migration of a phosphonate diester group. The reaction pr...

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Bibliographic Details
Published in:Tetrahedron letters 2018-05, Vol.59 (20), p.1955-1957
Main Authors: Tasgin, Dilek Isik, Unaleroglu, Canan
Format: Article
Language:English
Subjects:
Intramolecular migration
N-phosphorylation
Phosphonates
Pyrrole
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Summary:[Display omitted] •Migration of phosphonate group.•Synthesis of N-phosphorylated pyrroles.•An intramolecular migration of a phosphonate diester group. A new synthetic method is reported for the N-phosphorylation of pyrroles via intramolecular migration of a phosphonate diester group. The reaction proceeds under mild conditions and produces N-phosphorylated pyrrole derivatives in moderate to good yields.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2018.04.022