Stereoselective synthesis of C12–C21 common fragment of thermolides 1–5

[Display omitted] A highly stereoselective synthesis of C12–C21 common fragment of thermolides 1–5 has been described. The salient features of the synthesis are the utilization of desymmetrization protocol, Barton-McCombie reaction, Brown’s asymmetric allylation and Wacker oxidation.

Saved in:
Bibliographic Details
Published in:Tetrahedron letters 2018-07, Vol.59 (29), p.2828-2830
Main Authors: Satyanarayana, Vavilapalli, Chaithanya Kumar, Gavireddy, Muralikrishna, Katta, Singh Yadav, Jhillu
Format: Article
Language:English
Subjects:
Barton-McCombie reaction
Brown’s allylation
Desymmetrization
Nematodes
Wacker oxidation
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:[Display omitted] A highly stereoselective synthesis of C12–C21 common fragment of thermolides 1–5 has been described. The salient features of the synthesis are the utilization of desymmetrization protocol, Barton-McCombie reaction, Brown’s asymmetric allylation and Wacker oxidation.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2018.06.020