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The application of coffee-ring effect in analytical chemistry

Coffee-ring effect is an omnipresent phenomenon, it features the circular deposition on the surface after the evaporation of a droplet containing particles. Ever since the seminal report of coffee-ring effect in 1997 from Deegan (Nature 1997, 389 (6653), 827–829), coffee-ring effect related studies...

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Published in:TrAC, Trends in analytical chemistry (Regular ed.) Trends in analytical chemistry (Regular ed.), 2022-12, Vol.157, p.116752, Article 116752
Main Authors: Yang, Mingwei, Chen, Dejian, Hu, Jie, Zheng, Xinyu, Lin, Zu-Jin, Zhu, Haomiao
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Language:English
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description Coffee-ring effect is an omnipresent phenomenon, it features the circular deposition on the surface after the evaporation of a droplet containing particles. Ever since the seminal report of coffee-ring effect in 1997 from Deegan (Nature 1997, 389 (6653), 827–829), coffee-ring effect related studies have been thriving in various fields. Coffee-ring effect is a spontaneous phenomenon, the capillary flow from the center to the edge of droplet pushes all solute towards the droplet's edge. Therefore, any process involving small droplets especially in the analytical chemistry has to deal with coffee-ring effect. This review aims to offer an in-depth understanding of coffee-ring effect in analytical chemistry, includes the formation mechanism, controlling factors, as well as categorized applications based on the essence of factors. Lastly, the limitation and the future trends of this technique in analytical chemistry are discussed, offering our insights on the development of this technique and aiming to promote the application of this technique. •An in-depth decipher of coffee-ring effect mechanism.•Categorized applications based on the essence of coffee-ring effect.•Regular coffee-ring effect as an unique sample enrichment approach.•Various approaches for the coffee-ring effect suppression.
doi_str_mv 10.1016/j.trac.2022.116752
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subjects Coffee-ring effect
Coffee-ring effect suppression
Colloidal interface
Colorimetric analysis
Deposition patterns
Inwards coffee-ring effect
MALDI-MS
Microarray analysis
SERS
title The application of coffee-ring effect in analytical chemistry
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