Synthesis and X-ray diffraction data of N 1 , N 2 -di(2-hydroxy)benzylidenbenzene-1,2-di-imine, C 20 H 16 N 2 O 2

The Schiff base N 1 , N 2 -di(2-hydroxy)benzylidenebenzene-1,2-di-imine was prepared from salicylaldehyde and 1,2-diaminobenzene by reflux in ethanol for 6 h obtaining an orange crystalline solid. The Schiff base solid was separated by filtration and washed with ethanol and ethylic ether, and finall...

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Bibliographic Details
Published in:Powder diffraction 2018-03, Vol.33 (1), p.66-69
Main Authors: Camargo, H. A., Rosas, C. C., Henao, J. A., Castellanos, N. J.
Format: Article
Language:English
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Summary:The Schiff base N 1 , N 2 -di(2-hydroxy)benzylidenebenzene-1,2-di-imine was prepared from salicylaldehyde and 1,2-diaminobenzene by reflux in ethanol for 6 h obtaining an orange crystalline solid. The Schiff base solid was separated by filtration and washed with ethanol and ethylic ether, and finally, it was dried in a vacuum system for 2 h. The X-ray powder diffraction pattern for this new compound showed that the crystalline compound belongs to the monoclinic system and space group P 2 1 / c (No. 14) with refined unit-cell parameters a = 5.9672 (7) Å, b = 16.561 (1) Å, c = 16.337 (2) Å, β = 91.41° (1). The volume of the unit cell is V = 1614.1 (2) Å 3 .
ISSN:0885-7156
1945-7413
DOI:10.1017/S0885715618000027