Multifunctional Interpenetrated 3D Supramolecular Structure Based on 1D Coordination Polymers: Selective Adsorption, Magnetism, Optical Property, Theoretical Analysis, and Electrical Conductivity

• Published in: Crystal growth & design 2023-10, Vol.23 (10), p.7066-7075
• Main Authors: Dubey, Soumen Kumar, Biswas, Biplab, Halder, Dibakar, Mallick, Suman, Saha, Indrajit, Gupta, Kajal, Giri, Sanjib, Patra, Abhay Shankar, Rizzoli, Corrado, Meikap, Ajit Kumar, Bhattacharjee, Subham, Saha, Rajat
• Format: Article
• Language: English
• ISSN: 1528-7483; 1528-7505
• DOI: 10.1021/acs.cgd.3c00175

A paddle-wheel-based multifunctional 1D coordination polymer (CP) {[Cu2(4-Cl-Bz)4(4,4′-bipy)]­(DMF)2} n (where 4-Cl-BzH = 4-chlorobenzoic acid, 4,4′-bipy = 4,4′-bipyridine, and DMF = dimethylformamide), (complex 1) have been synthesized via the solvothermal method and characterized by single-crystal X-ray diffraction analysis along with other spectroscopic studies. Structural analysis shows that 1 crystallizes in the tetragonal P4 /ncc space group and 1D coordination chains are formed by connecting [Cu2(4-Cl-Bz)4] paddle wheel units using 4,4′-bipy moieties along the crystallographic c axis. These 1D coordination chains are assembled to each other through weak π···π interactions to form interpenetrated 3D supramolecular structure, forming channels along the [1 1 0] and [−1 1 0] direction hosting DMF molecules. Hirshfeld surface analysis and corresponding 2D fingerprint plots indicate that π···π interaction is the major interaction among the coordination chains. Thermal analysis shows that guest DMF molecules are released within the temperature range of 70–150 °C and powder X-ray diffraction (PXRD) analysis reveals the quenching of the void space after removal of the solvent molecules. The desolvated framework selectively adsorbs CO2 over N2. The magneto-luminescent behavior of the framework has also been studied. This π-induced 3D supramolecular complex shows semiconducting behavior and conductivity increases upon desolvation.