Diamond Crystallization from an Antimony–Carbon System under High Pressure and Temperature

We report the results of an experimental study on diamond crystallization in the Sb–C system under HPHT conditions. The experiments were run at pressures of 6.3 and 7.5 GPa in the temperature range of 1500–1800 °C for 1 to 40 h. Diamond crystallization via spontaneous nucleation and growth on the se...

Full description

Saved in:
Bibliographic Details
Published in:Crystal growth & design 2015-05, Vol.15 (5), p.2539-2544
Main Authors: Palyanov, Yuri N, Borzdov, Yuri M, Kupriyanov, Igor N, Bataleva, Yuliya V, Khokhryakov, Alexander F, Sokol, Alexander G
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a277t-f3d5968316993cff0c1b374a586c693363260529ed17c4503b3d536c7c8d5f7c3
cites cdi_FETCH-LOGICAL-a277t-f3d5968316993cff0c1b374a586c693363260529ed17c4503b3d536c7c8d5f7c3
container_end_page 2544
container_issue 5
container_start_page 2539
container_title Crystal growth & design
container_volume 15
creator Palyanov, Yuri N
Borzdov, Yuri M
Kupriyanov, Igor N
Bataleva, Yuliya V
Khokhryakov, Alexander F
Sokol, Alexander G
description We report the results of an experimental study on diamond crystallization in the Sb–C system under HPHT conditions. The experiments were run at pressures of 6.3 and 7.5 GPa in the temperature range of 1500–1800 °C for 1 to 40 h. Diamond crystallization via spontaneous nucleation and growth on the seed crystals has been established. It is shown that the kinetic factor plays a crucial role in diamond crystallization in the Sb–C system. For run duration of 40 h the minimal P–T parameters of diamond growth on the seed crystals are found to be 6.3 GPa and 1500 °C, while the minimal parameters for spontaneous nucleation are 7.5 GPa and 1600 °C.
doi_str_mv 10.1021/acs.cgd.5b00310
format article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acs_cgd_5b00310</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>h67374389</sourcerecordid><originalsourceid>FETCH-LOGICAL-a277t-f3d5968316993cff0c1b374a586c693363260529ed17c4503b3d536c7c8d5f7c3</originalsourceid><addsrcrecordid>eNp1kM9Kw0AQhxdRsFbPXvcuaWcz3d3kWKK2QkHBehPCZv_UlCYpu-mhnnwH39AncUvr0dPMMN9vGD5CbhmMGKRsrHQY6ZUZ8QoAGZyRAeNplkgO_Pyvn2R4Sa5CWAOAFIgD8n5fq6ZrDS38PvRqs6k_VV93LXW-a6hq6bTt6wjsf76-C-WruHmNoG3orjXW03m9-qAv3oaw8zbyhi5ts7Ve9XG-JhdObYK9OdUheXt8WBbzZPE8eyqmi0SlUvaJQ8NzkSETeY7aOdCsQjlRPBNa5IgCUwE8za1hUk84YBUDKLTUmeFOahyS8fGu9l0I3rpy6-tG-X3JoDzIKaOcMsopT3Ji4u6YOCzW3c638b9_6V_Pbmj2</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Diamond Crystallization from an Antimony–Carbon System under High Pressure and Temperature</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Palyanov, Yuri N ; Borzdov, Yuri M ; Kupriyanov, Igor N ; Bataleva, Yuliya V ; Khokhryakov, Alexander F ; Sokol, Alexander G</creator><creatorcontrib>Palyanov, Yuri N ; Borzdov, Yuri M ; Kupriyanov, Igor N ; Bataleva, Yuliya V ; Khokhryakov, Alexander F ; Sokol, Alexander G</creatorcontrib><description>We report the results of an experimental study on diamond crystallization in the Sb–C system under HPHT conditions. The experiments were run at pressures of 6.3 and 7.5 GPa in the temperature range of 1500–1800 °C for 1 to 40 h. Diamond crystallization via spontaneous nucleation and growth on the seed crystals has been established. It is shown that the kinetic factor plays a crucial role in diamond crystallization in the Sb–C system. For run duration of 40 h the minimal P–T parameters of diamond growth on the seed crystals are found to be 6.3 GPa and 1500 °C, while the minimal parameters for spontaneous nucleation are 7.5 GPa and 1600 °C.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/acs.cgd.5b00310</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Crystal growth &amp; design, 2015-05, Vol.15 (5), p.2539-2544</ispartof><rights>Copyright © American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a277t-f3d5968316993cff0c1b374a586c693363260529ed17c4503b3d536c7c8d5f7c3</citedby><cites>FETCH-LOGICAL-a277t-f3d5968316993cff0c1b374a586c693363260529ed17c4503b3d536c7c8d5f7c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Palyanov, Yuri N</creatorcontrib><creatorcontrib>Borzdov, Yuri M</creatorcontrib><creatorcontrib>Kupriyanov, Igor N</creatorcontrib><creatorcontrib>Bataleva, Yuliya V</creatorcontrib><creatorcontrib>Khokhryakov, Alexander F</creatorcontrib><creatorcontrib>Sokol, Alexander G</creatorcontrib><title>Diamond Crystallization from an Antimony–Carbon System under High Pressure and Temperature</title><title>Crystal growth &amp; design</title><addtitle>Cryst. Growth Des</addtitle><description>We report the results of an experimental study on diamond crystallization in the Sb–C system under HPHT conditions. The experiments were run at pressures of 6.3 and 7.5 GPa in the temperature range of 1500–1800 °C for 1 to 40 h. Diamond crystallization via spontaneous nucleation and growth on the seed crystals has been established. It is shown that the kinetic factor plays a crucial role in diamond crystallization in the Sb–C system. For run duration of 40 h the minimal P–T parameters of diamond growth on the seed crystals are found to be 6.3 GPa and 1500 °C, while the minimal parameters for spontaneous nucleation are 7.5 GPa and 1600 °C.</description><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kM9Kw0AQhxdRsFbPXvcuaWcz3d3kWKK2QkHBehPCZv_UlCYpu-mhnnwH39AncUvr0dPMMN9vGD5CbhmMGKRsrHQY6ZUZ8QoAGZyRAeNplkgO_Pyvn2R4Sa5CWAOAFIgD8n5fq6ZrDS38PvRqs6k_VV93LXW-a6hq6bTt6wjsf76-C-WruHmNoG3orjXW03m9-qAv3oaw8zbyhi5ts7Ve9XG-JhdObYK9OdUheXt8WBbzZPE8eyqmi0SlUvaJQ8NzkSETeY7aOdCsQjlRPBNa5IgCUwE8za1hUk84YBUDKLTUmeFOahyS8fGu9l0I3rpy6-tG-X3JoDzIKaOcMsopT3Ji4u6YOCzW3c638b9_6V_Pbmj2</recordid><startdate>20150506</startdate><enddate>20150506</enddate><creator>Palyanov, Yuri N</creator><creator>Borzdov, Yuri M</creator><creator>Kupriyanov, Igor N</creator><creator>Bataleva, Yuliya V</creator><creator>Khokhryakov, Alexander F</creator><creator>Sokol, Alexander G</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20150506</creationdate><title>Diamond Crystallization from an Antimony–Carbon System under High Pressure and Temperature</title><author>Palyanov, Yuri N ; Borzdov, Yuri M ; Kupriyanov, Igor N ; Bataleva, Yuliya V ; Khokhryakov, Alexander F ; Sokol, Alexander G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a277t-f3d5968316993cff0c1b374a586c693363260529ed17c4503b3d536c7c8d5f7c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Palyanov, Yuri N</creatorcontrib><creatorcontrib>Borzdov, Yuri M</creatorcontrib><creatorcontrib>Kupriyanov, Igor N</creatorcontrib><creatorcontrib>Bataleva, Yuliya V</creatorcontrib><creatorcontrib>Khokhryakov, Alexander F</creatorcontrib><creatorcontrib>Sokol, Alexander G</creatorcontrib><collection>CrossRef</collection><jtitle>Crystal growth &amp; design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Palyanov, Yuri N</au><au>Borzdov, Yuri M</au><au>Kupriyanov, Igor N</au><au>Bataleva, Yuliya V</au><au>Khokhryakov, Alexander F</au><au>Sokol, Alexander G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diamond Crystallization from an Antimony–Carbon System under High Pressure and Temperature</atitle><jtitle>Crystal growth &amp; design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2015-05-06</date><risdate>2015</risdate><volume>15</volume><issue>5</issue><spage>2539</spage><epage>2544</epage><pages>2539-2544</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>We report the results of an experimental study on diamond crystallization in the Sb–C system under HPHT conditions. The experiments were run at pressures of 6.3 and 7.5 GPa in the temperature range of 1500–1800 °C for 1 to 40 h. Diamond crystallization via spontaneous nucleation and growth on the seed crystals has been established. It is shown that the kinetic factor plays a crucial role in diamond crystallization in the Sb–C system. For run duration of 40 h the minimal P–T parameters of diamond growth on the seed crystals are found to be 6.3 GPa and 1500 °C, while the minimal parameters for spontaneous nucleation are 7.5 GPa and 1600 °C.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.cgd.5b00310</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1528-7483
ispartof Crystal growth & design, 2015-05, Vol.15 (5), p.2539-2544
issn 1528-7483
1528-7505
language eng
recordid cdi_crossref_primary_10_1021_acs_cgd_5b00310
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
title Diamond Crystallization from an Antimony–Carbon System under High Pressure and Temperature
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T12%3A41%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Diamond%20Crystallization%20from%20an%20Antimony%E2%80%93Carbon%20System%20under%20High%20Pressure%20and%20Temperature&rft.jtitle=Crystal%20growth%20&%20design&rft.au=Palyanov,%20Yuri%20N&rft.date=2015-05-06&rft.volume=15&rft.issue=5&rft.spage=2539&rft.epage=2544&rft.pages=2539-2544&rft.issn=1528-7483&rft.eissn=1528-7505&rft_id=info:doi/10.1021/acs.cgd.5b00310&rft_dat=%3Cacs_cross%3Eh67374389%3C/acs_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a277t-f3d5968316993cff0c1b374a586c693363260529ed17c4503b3d536c7c8d5f7c3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true