Construction of Noninterpenetrating and Interpenetrating (4-Fold and 8‑Fold) 3‑D Cd(II) Networks with Tris(1,2,4-triazol-4-yl)phenyl)amine Modulated by Aromatic Dicarboxylate Coligands

• Published in: Crystal growth & design 2016-10, Vol.16 (10), p.5859-5868
• Main Authors: Shen, Yu, Fan, Cong-Cong, Wei, Yu-Zhen, Du, Jie, Zhu, Hai-Bin, Zhao, Yue
• Format: Article
• Language: English
• ISSN: 1528-7483; 1528-7505
• DOI: 10.1021/acs.cgd.6b00931

Three Cd­(II)-based coordination polymers 1–3 with unique structures and topologies have been successfully constructed under solvothermal conditions by use of a newly designed N-containing rigid triangular ligand tris­(4-(4H-1,2,4-triazol-4-yl)­phenyl)­amine (TTPA-4), wherein the structural interpenetration can be modulated by aromatic dicarboxylate coligands including thiophene-2,5-dicarboxylic acid (TDA) and terephthalic acid (TPA). Without using coligands, a noninterpenetrating porous 3-D network of 1 with nia topology was obtained. With the aid of the V-shaped TDA coligand, a 4-fold interpenetrating 3-D network of 2 resulted that is built from (2,3,7)-connecting (42.6)­(44.6.88.104.124)­(4)2 net. In the presence of the linear TPA auxiliary ligand, an 8-fold interpenetrating 3-D network of 3 was produced that is assembled by 3-connecting uninodal srs net. Particularly, compound 1 displays interesting dual function as the result of its unique structural attributes, which not only shows superb sensitivity for nitroaromatics (NACs) with phenolic group but also impressive removal capabilities of toxic Cr2O7 2– oxoanion pollutant from aqueous solution.