Antimony-Assisted Assembly of Basic Supertetrahedral Clusters into Heterometallic Chalcogenide Supraclusters

Reported here are two new heterometallic chalcogenide supraclusters ([Ga56Sb16S136] and [In36Sb6S75]), which present new self-assembly modes of basic supertetraheral clusters with the assistance of antimony ions. This work demonstrates the crucial role of the added metal ions with nontetrahedral coo...

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Bibliographic Details
Published in:Inorganic chemistry 2020-09, Vol.59 (18), p.13000-13004
Main Authors: Ding, Yayun, Zhang, Jiaxu, Liu, Chengdong, Wang, Xiao-Li, Wu, Zhou, Wang, Xiang, Zhou, Rui, Li, Dong-Sheng, Wu, Tao
Format: Article
Language:English
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Summary:Reported here are two new heterometallic chalcogenide supraclusters ([Ga56Sb16S136] and [In36Sb6S75]), which present new self-assembly modes of basic supertetraheral clusters with the assistance of antimony ions. This work demonstrates the crucial role of the added metal ions with nontetrahedral coordination geometry in developing supertetrahedral-cluster-based supraclusters with a new level of complexity.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.0c02097