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Beyond Crystal Engineering: Significant Enhancement of C 2 H 2 /CO 2 Separation by Constructing Composite Material

Different from the established crystal engineering method for enhancing gas-separation performance, we demonstrate herein a distinct approach. In contrast to the pristine MOF (metal-organic framework) material, the C H /CO separation ability for the resultant Ag NPs (nanoparticle)@Fe O @MOF composit...

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Bibliographic Details
Published in:Inorganic chemistry 2018-04, Vol.57 (7), p.3679-3682
Main Authors: Wu, Hui Qiong, Yan, Chang Sheng, Luo, Feng, Krishna, Rajamani
Format: Article
Language:English
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Summary:Different from the established crystal engineering method for enhancing gas-separation performance, we demonstrate herein a distinct approach. In contrast to the pristine MOF (metal-organic framework) material, the C H /CO separation ability for the resultant Ag NPs (nanoparticle)@Fe O @MOF composite material, estimated from breakthrough calculations, is greatly enhanced by 2 times, and further magnified up to 3 times under visible light irradiation.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.8b00341