Step-by-Step Assembly of Metal-Organic Frameworks from Trinuclear Cu 3 Clusters

Two novel metal-organic frameworks (MOFs), HBNU-1 and HBNU-2, have been synthesized successfully. We adopt a step-by-step assembly strategy, which first synthesize the Cu cluster Cu (μ -OH)(pz) (CH COO) (Hpz), and then react it with H BDC under different conditions to form final frameworks. In both...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry 2019-01, Vol.58 (1), p.199-203
Main Authors: Zhao, Nian, Yang, Lun, Pan, Qiyun, Han, Juanjuan, Li, Xiang, Liu, Meifeng, Wang, Yu, Wang, Xiuzhang, Pan, Qinhe, Zhu, Guangshan
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Two novel metal-organic frameworks (MOFs), HBNU-1 and HBNU-2, have been synthesized successfully. We adopt a step-by-step assembly strategy, which first synthesize the Cu cluster Cu (μ -OH)(pz) (CH COO) (Hpz), and then react it with H BDC under different conditions to form final frameworks. In both MOF structures, the Cu clusters are maintained, although certain differences are observed. Compared with HBNU-1, the Cu cluster dimerizes into Cu cluster in HBNU-2. With this step-by-step cluster assembly strategy, MOF structure predicting becomes possible and may give some reference for MOF structure designing.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.8b02158