Nickel-Iron Dithiolato Hydrides Derived from H 2 Activation by Their μ-Hydroxo Ligand-Containing Analogues

Here, we describe the synthesis and characterization of the two μ-hydrido models of [NiFe]H ases prepared from a new type of H activation by the corresponding two μ-hydroxo models. In addition, another μ-hydrido model prepared by the anionic exchange between one of the two μ-hydrido models and KPF i...

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Bibliographic Details
Published in:Inorganic chemistry 2019-01, Vol.58 (1), p.39-42
Main Authors: Song, Li-Cheng, Yang, Xi-Yue, Gao, Xiu-Yun, Cao, Meng
Format: Article
Language:English
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Summary:Here, we describe the synthesis and characterization of the two μ-hydrido models of [NiFe]H ases prepared from a new type of H activation by the corresponding two μ-hydroxo models. In addition, another μ-hydrido model prepared by the anionic exchange between one of the two μ-hydrido models and KPF is also reported. Interestingly, the synthesis of the two μ-hydrido models from H activation represents the first functional modeling of the H activation catalyzed by the [NiFe]H ase (Ni-SIr) state to give the Ni-R state.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.8b02648