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2 H -Pyran-2-one-Functionalized Diketopyrrolopyrrole Dye: Design, Synthesis, and Explosives Sensor
In this work, a 2 -pyran-2-one-functionalized diketopyrrolopyrrole (DPP) (coded as receptor ) was designed, synthesized, and fully characterized by various spectroscopic methods. The physical properties of molecular architecture were studied employing theoretical calculations. Receptor was elegantly...
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Published in: | Journal of organic chemistry 2024-05, Vol.89 (9), p.5917-5926 |
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Main Authors: | , , , , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | In this work, a 2
-pyran-2-one-functionalized diketopyrrolopyrrole (DPP) (coded as receptor
) was designed, synthesized, and fully characterized by various spectroscopic methods. The physical properties of molecular architecture
were studied employing theoretical calculations. Receptor
was elegantly scrutinized for the sensing of explosive nitroaromatic compounds (NACs). Receptor
exhibited detection of nitro explosives, i.e., picric acid (PA), 2,4-dinitrophenol (DNP), and nitrophenol (NP),
the fluorescence quenching mechanism. The Stern-Volmer equation was employed to evaluate the effectiveness of the quenching process. It was found that
exhibited a detection limit of about 7.58 × 10
, 8.35 × 10
, and 9.05 × 10
M toward PA, DNP, and NP, respectively. The influence of interfering metal ions and anions on PA detection was investigated thoroughly. Furthermore, receptor
based low-cost fluorescent thin-layer chromatography (TLC) plates were developed for the recognition of PA. |
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ISSN: | 0022-3263 1520-6904 |
DOI: | 10.1021/acs.joc.2c01439 |