X 3 Σ g - → b 1 Σ g + Absorption Spectra of Molecular Oxygen in Liquid Organic Solvents at Atmospheric Pressure

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2022-06, Vol.126 (23), p.3839-3845
• Main Authors: Bregnhøj, Mikkel, McLoughlin, Ciaran K, Breitenbach, Thomas, Ogilby, Peter R
• Format: Article
• Language: English
• ISSN: 1089-5639; 1520-5215
• DOI: 10.1021/acs.jpca.2c03053

Spectra and absorption coefficients of the forbidden 765 nm X Σ → b Σ transition of molecular oxygen dissolved in organic solvents at atmospheric pressure were recorded over a 5 m path length using a liquid waveguide capillary cell. The results show that it is possible to investigate this weak near-infrared absorption transition in a common liquid hydrocarbon solvent without the need for a potentially dangerous high oxygen pressure. Proof-of-principle data from benzene, toluene, chlorobenzene, bromobenzene, and iodobenzene reveal a pronounced heavy atom effect on this spin-forbidden transition. For example, the absorption coefficient at the band maximum in iodobenzene, (28.9 ± 3.3) × 10 M cm , is approximately 21 times larger than that in benzene, (1.4 ± 0.1) × 10 M cm . These absorption measurements corroborate results obtained from O (X Σ ) → O (b Σ ) excitation spectra of O (a Δ ) → O (X Σ ) phosphorescence, which depended on data from a plethora of convoluted experiments. Spectroscopic studies of molecular oxygen in liquid solvents can help evaluate aspects of the seminal Strickler-Berg approach to treat the effect of solvent on Einstein's A and B coefficients for radiative transitions. In particular, our present results are a key step toward using the O (X Σ ) → O (b Σ ) transition to evaluate the speculated limiting condition of applying the Strickler-Berg treatment to a highly forbidden process. This latter issue is but one example of how an arguably simple homonuclear diatomic molecule continues to aid the scientific community by providing fundamental physical insight.