Revisiting the Disorder–Order Transition in 1‑X-Adamantane Plastic Crystals: Rayleigh Wing, Boson Peak, and Lattice Phonons

In this paper, we revisit the disorder–order transition in 1-chloro-adamantane and present new data on 1-bromo-adamantane. Rayleigh scattering and Raman-active optical lattice phonons are used to easily characterize the phase change. Unlike Cl-derivative, the Br-derivative shows a semiordered struct...

Full description

Saved in:
Bibliographic Details
Published in:Journal of physical chemistry. C 2021-04, Vol.125 (13), p.7384-7391
Main Authors: Salzillo, Tommaso, Girlando, Alberto, Brillante, Aldo
Format: Article
Language:English
Subjects:
C: Physical Properties of Materials and Interfaces
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a322t-b5147c22ebe964dafb73ad14f41038f85ce59cc810b821be0a359358c14b9afd3
cites cdi_FETCH-LOGICAL-a322t-b5147c22ebe964dafb73ad14f41038f85ce59cc810b821be0a359358c14b9afd3
container_end_page 7391
container_issue 13
container_start_page 7384
container_title Journal of physical chemistry. C
container_volume 125
creator Salzillo, Tommaso
Girlando, Alberto
Brillante, Aldo
description In this paper, we revisit the disorder–order transition in 1-chloro-adamantane and present new data on 1-bromo-adamantane. Rayleigh scattering and Raman-active optical lattice phonons are used to easily characterize the phase change. Unlike Cl-derivative, the Br-derivative shows a semiordered structure in the vicinity of ambient P,T conditions, which is peculiar of this compound and seems to be due to a more reduced rotational disorder of the Br-derivative with respect to the other halogen-adamantanes. The semiordered phase is briefly discussed in terms of its Rayleigh Wing and Boson peak.
doi_str_mv 10.1021/acs.jpcc.1c00239
format article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acs_jpcc_1c00239</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>a783989991</sourcerecordid><originalsourceid>FETCH-LOGICAL-a322t-b5147c22ebe964dafb73ad14f41038f85ce59cc810b821be0a359358c14b9afd3</originalsourceid><addsrcrecordid>eNp1kM1OAjEUhRujiYjuXfYBGOzP1Jlxh_ibkEAIRneTO50OFKEl7WDCSl7B-IY8iR0h7lydm5zzndwchC4p6VLC6BVI352vpOxSSQjj2RFq0YyzKImFOP674-QUnXk_J0RwQnkLfY7Vh_a61maK65nCd9pbVyq3234PG8UTB6bxrcHaYLrbfr1FvRKWYGowCo8W4Gstcd9tfA0Lf4PHsFkoPZ3h19DZwbfWB3Sk4L2DwZR4AHXIB3BmjTX-HJ1UAVMXB22jl4f7Sf8pGgwfn_u9QQScsToqBI0TyZgqVHYdl1AVCYeSxlVMCU-rVEglMilTSoqU0UIR4CLjIpU0LjKoSt5GZN8rnfXeqSpfOb0Et8kpyZsB8zBg3gyYHwYMSGeP_Dp27Ux48P_4D1JNd88</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Revisiting the Disorder–Order Transition in 1‑X-Adamantane Plastic Crystals: Rayleigh Wing, Boson Peak, and Lattice Phonons</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Salzillo, Tommaso ; Girlando, Alberto ; Brillante, Aldo</creator><creatorcontrib>Salzillo, Tommaso ; Girlando, Alberto ; Brillante, Aldo</creatorcontrib><description>In this paper, we revisit the disorder–order transition in 1-chloro-adamantane and present new data on 1-bromo-adamantane. Rayleigh scattering and Raman-active optical lattice phonons are used to easily characterize the phase change. Unlike Cl-derivative, the Br-derivative shows a semiordered structure in the vicinity of ambient P,T conditions, which is peculiar of this compound and seems to be due to a more reduced rotational disorder of the Br-derivative with respect to the other halogen-adamantanes. The semiordered phase is briefly discussed in terms of its Rayleigh Wing and Boson peak.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/acs.jpcc.1c00239</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>C: Physical Properties of Materials and Interfaces</subject><ispartof>Journal of physical chemistry. C, 2021-04, Vol.125 (13), p.7384-7391</ispartof><rights>2021 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a322t-b5147c22ebe964dafb73ad14f41038f85ce59cc810b821be0a359358c14b9afd3</citedby><cites>FETCH-LOGICAL-a322t-b5147c22ebe964dafb73ad14f41038f85ce59cc810b821be0a359358c14b9afd3</cites><orcidid>0000-0002-9737-2809 ; 0000-0003-1887-709X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Salzillo, Tommaso</creatorcontrib><creatorcontrib>Girlando, Alberto</creatorcontrib><creatorcontrib>Brillante, Aldo</creatorcontrib><title>Revisiting the Disorder–Order Transition in 1‑X-Adamantane Plastic Crystals: Rayleigh Wing, Boson Peak, and Lattice Phonons</title><title>Journal of physical chemistry. C</title><addtitle>J. Phys. Chem. C</addtitle><description>In this paper, we revisit the disorder–order transition in 1-chloro-adamantane and present new data on 1-bromo-adamantane. Rayleigh scattering and Raman-active optical lattice phonons are used to easily characterize the phase change. Unlike Cl-derivative, the Br-derivative shows a semiordered structure in the vicinity of ambient P,T conditions, which is peculiar of this compound and seems to be due to a more reduced rotational disorder of the Br-derivative with respect to the other halogen-adamantanes. The semiordered phase is briefly discussed in terms of its Rayleigh Wing and Boson peak.</description><subject>C: Physical Properties of Materials and Interfaces</subject><issn>1932-7447</issn><issn>1932-7455</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kM1OAjEUhRujiYjuXfYBGOzP1Jlxh_ibkEAIRneTO50OFKEl7WDCSl7B-IY8iR0h7lydm5zzndwchC4p6VLC6BVI352vpOxSSQjj2RFq0YyzKImFOP674-QUnXk_J0RwQnkLfY7Vh_a61maK65nCd9pbVyq3234PG8UTB6bxrcHaYLrbfr1FvRKWYGowCo8W4Gstcd9tfA0Lf4PHsFkoPZ3h19DZwbfWB3Sk4L2DwZR4AHXIB3BmjTX-HJ1UAVMXB22jl4f7Sf8pGgwfn_u9QQScsToqBI0TyZgqVHYdl1AVCYeSxlVMCU-rVEglMilTSoqU0UIR4CLjIpU0LjKoSt5GZN8rnfXeqSpfOb0Et8kpyZsB8zBg3gyYHwYMSGeP_Dp27Ux48P_4D1JNd88</recordid><startdate>20210408</startdate><enddate>20210408</enddate><creator>Salzillo, Tommaso</creator><creator>Girlando, Alberto</creator><creator>Brillante, Aldo</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-9737-2809</orcidid><orcidid>https://orcid.org/0000-0003-1887-709X</orcidid></search><sort><creationdate>20210408</creationdate><title>Revisiting the Disorder–Order Transition in 1‑X-Adamantane Plastic Crystals: Rayleigh Wing, Boson Peak, and Lattice Phonons</title><author>Salzillo, Tommaso ; Girlando, Alberto ; Brillante, Aldo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a322t-b5147c22ebe964dafb73ad14f41038f85ce59cc810b821be0a359358c14b9afd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>C: Physical Properties of Materials and Interfaces</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Salzillo, Tommaso</creatorcontrib><creatorcontrib>Girlando, Alberto</creatorcontrib><creatorcontrib>Brillante, Aldo</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of physical chemistry. C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Salzillo, Tommaso</au><au>Girlando, Alberto</au><au>Brillante, Aldo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Revisiting the Disorder–Order Transition in 1‑X-Adamantane Plastic Crystals: Rayleigh Wing, Boson Peak, and Lattice Phonons</atitle><jtitle>Journal of physical chemistry. C</jtitle><addtitle>J. Phys. Chem. C</addtitle><date>2021-04-08</date><risdate>2021</risdate><volume>125</volume><issue>13</issue><spage>7384</spage><epage>7391</epage><pages>7384-7391</pages><issn>1932-7447</issn><eissn>1932-7455</eissn><abstract>In this paper, we revisit the disorder–order transition in 1-chloro-adamantane and present new data on 1-bromo-adamantane. Rayleigh scattering and Raman-active optical lattice phonons are used to easily characterize the phase change. Unlike Cl-derivative, the Br-derivative shows a semiordered structure in the vicinity of ambient P,T conditions, which is peculiar of this compound and seems to be due to a more reduced rotational disorder of the Br-derivative with respect to the other halogen-adamantanes. The semiordered phase is briefly discussed in terms of its Rayleigh Wing and Boson peak.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.jpcc.1c00239</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-9737-2809</orcidid><orcidid>https://orcid.org/0000-0003-1887-709X</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1932-7447
ispartof Journal of physical chemistry. C, 2021-04, Vol.125 (13), p.7384-7391
issn 1932-7447
1932-7455
language eng
recordid cdi_crossref_primary_10_1021_acs_jpcc_1c00239
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects C: Physical Properties of Materials and Interfaces
title Revisiting the Disorder–Order Transition in 1‑X-Adamantane Plastic Crystals: Rayleigh Wing, Boson Peak, and Lattice Phonons
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T03%3A27%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Revisiting%20the%20Disorder%E2%80%93Order%20Transition%20in%201%E2%80%91X-Adamantane%20Plastic%20Crystals:%20Rayleigh%20Wing,%20Boson%20Peak,%20and%20Lattice%20Phonons&rft.jtitle=Journal%20of%20physical%20chemistry.%20C&rft.au=Salzillo,%20Tommaso&rft.date=2021-04-08&rft.volume=125&rft.issue=13&rft.spage=7384&rft.epage=7391&rft.pages=7384-7391&rft.issn=1932-7447&rft.eissn=1932-7455&rft_id=info:doi/10.1021/acs.jpcc.1c00239&rft_dat=%3Cacs_cross%3Ea783989991%3C/acs_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a322t-b5147c22ebe964dafb73ad14f41038f85ce59cc810b821be0a359358c14b9afd3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true