A Near-Room-Temperature Hybrid Organic–Inorganic Lead Halide Perovskite Ferroelectric [BrCH2CH2N(CH3)3][PbBr3] and Its Flexible Composite Film

A hybrid organic–inorganic lead halide perovskite, [BrCH2CH2N­(CH3)3]­[PbBr3] (BEPbBr), obtained by matching a quasi-spherical (2-bromoethyl) trimethylammonium cation with an infinite one-dimensional zigzag [PbBr3]− anion chain, exhibits a reversible ferroelectric phase transition at 302/286 K. Swit...

Full description

Saved in:
Bibliographic Details
Published in:Journal of physical chemistry. C 2022-01, Vol.126 (1), p.728-736
Main Authors: Li, Duo-Fu, Deng, Xiang-Hong, Ma, Yu-Xiao, Liu, Dong-Sheng, Huang, Xi-Feng, Zhao, Xiao-Feng, Chen, Wen-Tong, Sui, Yan
Format: Article
Language:English
Subjects:
C: Physical Properties of Materials and Interfaces
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A hybrid organic–inorganic lead halide perovskite, [BrCH2CH2N­(CH3)3]­[PbBr3] (BEPbBr), obtained by matching a quasi-spherical (2-bromoethyl) trimethylammonium cation with an infinite one-dimensional zigzag [PbBr3]− anion chain, exhibits a reversible ferroelectric phase transition at 302/286 K. Switchable dielectric and ferroelectricity were observed accompanied by the order–disorder phase transition at near-room-temperature. Further, the ferroelectric BEPbBr was dispersed into a PVDF matrix to form flexible BEPbBr@PVDF composite films. The β-phase PVDF content in composite films was significantly improved without requiring complicated after-treatment, and the ferroelectricity was also greatly enhanced resulting from the induced ordered orientation by the interactions between BEPbBr and β-phase dominated PVDF. This finding may promote research on near-room-temperature multifunctional switching smart materials and wearable devices by utilizing molecular ferroelectrics and their flexible films.
ISSN:1932-7447
1932-7455
DOI:10.1021/acs.jpcc.1c08962