Molecular Self-Assembly Driven by On-Surface Reduction: Anthracene and Tetracene on Au(111)

• Published in: Journal of physical chemistry. C 2017-09, Vol.121 (37), p.20353-20358
• Main Authors: Krüger, Justus, Eisenhut, Frank, Lehmann, Thomas, Alonso, José M, Meyer, Jörg, Skidin, Dmitry, Ohmann, Robin, Ryndyk, Dmitry A, Pérez, Dolores, Guitián, Enrique, Peña, Diego, Moresco, Francesca, Cuniberti, Gianaurelio
• Format: Article
• Language: English
• ISSN: 1932-7447; 1932-7455
• DOI: 10.1021/acs.jpcc.7b06131

Epoxyacenes adsorbed on metal surfaces form acenes during thermally induced reduction in ultrahigh vacuum conditions. The incorporation of oxygen bridges into a hydrocarbon backbone leads to an enhanced stability of these molecular precursors under ambient condition; however, it has also a distinct influence on their adsorption and self-assembly on metal surfaces. Here, a low-temperature scanning tunneling microscopy (LT-STM) study of two different epoxyacenes on the Au(111) surface at submonolayer coverage is presented. Both molecules show self-assembly based on hydrogen bonding. While for the molecules with a single epoxy moiety nanostructures of three molecules are formed, extended molecular networks are achieved with two epoxy moieties and a slightly higher surface coverage. Upon annealing at 390 K, the molecules are reduced to the respective acene; however, both systems keep a similar assembled structure. The experimental STM images supported by theoretical calculations show that the self-assembly of the on-surface fabricated acenes is greatly influenced by the on-surface reaction and strongly differs from the adsorption pattern of directly deposited acenes, highlighting the importance of the cleaved oxygen in the self-assembly.