Co-Doped Ni 3 N Nanosheets with Electron Redistribution as Bifunctional Electrocatalysts for Efficient Water Splitting

• Published in: The journal of physical chemistry letters 2021-02, Vol.12 (6), p.1581-1587
• Main Authors: Wang, Meng, Ma, Wansen, Lv, Zepeng, Liu, Dong, Jian, Kailiang, Dang, Jie
• Format: Article
• Language: English
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.0c03804

Preparation of high-activity and earth-abundant bifunctional catalysts for efficient electrochemical water splitting are crucial and challenging. Herein, Co-doped Ni N nanosheets loaded on nickel foam (Co-Ni N) were synthesized. The as-prepared Co-Ni N exhibits excellent catalytic activity toward both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) in alkaline media. Density functional theory (DFT) calculation reveals that Co-Ni N with redistribution of electrons not only can facilitate the HER kinetics but also can regulate intermediates adsorption energies for OER. Specifically, the Co-Ni N exhibits high efficiency and stable catalytic activity, with an overpotential of only 30 and 270 mV at a current density of 10 mA cm for the HER and OER in 1 M KOH, respectively. This work provides strong evidence to the merit of Co doping to improve the innate electrochemical performance in bifunctional catalysts, which might have a common impact in many similar metal-metal nitride electrocatalysts.