Coupling of Elementary Electronic Excitations: Drawing Parallels Between Excitons and Plasmons

• Published in: The journal of physical chemistry letters 2018-02, Vol.9 (4), p.919-932
• Main Authors: Thomas, Reshmi, Kumar, Jatish, George, Jino, Shanthil, M, Naidu, G. Narmada, Swathi, R. S, Thomas, K. George
• Format: Article
• Language: English
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.7b01833

Recent advances in understanding the theoretical and experimental properties of excitons and plasmons have led to several technological breakthroughs. Though emerging from different schools of research, the parallels they possess both in their isolated and assembled forms are indeed interesting. Employing the larger framework of the dipolar coupling model, these aspects are discussed based on the excitonic transitions in chromophores and plasmonic resonances in noble metal nanostructures. The emergence of novel optical properties in linear, parallel, and helical assemblies of chromophores and nanostructures with varying separation distances, orientations, and interaction strengths of interacting dipolar components is discussed. The very high dipolar strengths of plasmonic transitions compared to the excitonic transitions, arising due to the collective nature of the electronic excitations in nanostructures, leads to the emergence of hot spots in plasmonically coupled assemblies. Correlations on the distance dependence of electric field with Raman signal enhancements have paved the way to the development of capillary tube-based plasmonic platforms for the detection of analytes.