Synthesis of Cyclic (Alkyl)(amino)carbene-Stabilized Copper–Iron Heterobimetallic Complexes and Their Application in Pyridine Hydroboration

In this report, we synthesized heterobimetallic complexes supported by cyclic and bicyclic (alkyl)­(amino)­carbenes (CAAC and Et BICAAC) [( Me2 CAAC)­CuFe­(η5-C5H5)­(CO)2]­(1) and [( Et BICAAC)­CuFe­(η5-C5H5)­(CO)2] (2), respectively, featuring an iron–copper bond. Complex 1 demonstrates catalytic a...

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Published in:Organometallics 2024-12, Vol.43 (23), p.3054-3061
Main Authors: Sharma, Ankita, Tiwari, Vikas, Yadav, Ritu, Das, Bindusagar, Majumder, Chinmoy, Das, Ayantika, Karmakar, Tarak, Kundu, Subrata
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container_end_page 3061
container_issue 23
container_start_page 3054
container_title Organometallics
container_volume 43
creator Sharma, Ankita
Tiwari, Vikas
Yadav, Ritu
Das, Bindusagar
Majumder, Chinmoy
Das, Ayantika
Karmakar, Tarak
Kundu, Subrata
description In this report, we synthesized heterobimetallic complexes supported by cyclic and bicyclic (alkyl)­(amino)­carbenes (CAAC and Et BICAAC) [( Me2 CAAC)­CuFe­(η5-C5H5)­(CO)2]­(1) and [( Et BICAAC)­CuFe­(η5-C5H5)­(CO)2] (2), respectively, featuring an iron–copper bond. Complex 1 demonstrates catalytic activity for selective 1,4-hydroboration reactions of pyridine derivatives. Detailed computational studies provide additional insights into the electronic structure of complexes 1 and 2 and elucidate the catalytic pathway.
doi_str_mv 10.1021/acs.organomet.4c00413
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title Synthesis of Cyclic (Alkyl)(amino)carbene-Stabilized Copper–Iron Heterobimetallic Complexes and Their Application in Pyridine Hydroboration
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