Hydroxyl Radical Control through Hydrogen Bonding: Photolysis of Platinum(IV)hydroxido Complexes with Intramolecular H‑Bonding

By introducing hydrogen-bonding groups into the coordination sphere of Pt­(IV) hydroxido complexes photogenerated hydroxyl radicals are tethered and directed to abstract a hydrogen atom from the ethyl group of a triethylphosphine ligand, even at 25 °C, to yield phosphaplatinacycle complexes.

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Bibliographic Details
Published in:Organometallics 2015-07, Vol.34 (14), p.3451-3454
Main Authors: Wickramasinghe, Lasantha A, Sharp, Paul R
Format: Article
Language:English
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Summary:By introducing hydrogen-bonding groups into the coordination sphere of Pt­(IV) hydroxido complexes photogenerated hydroxyl radicals are tethered and directed to abstract a hydrogen atom from the ethyl group of a triethylphosphine ligand, even at 25 °C, to yield phosphaplatinacycle complexes.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.5b00292