Improved Working Temperature and Capacitive Energy Density of Biaxially Oriented Polypropylene Films with Alumina Coating Layers

High-temperature dielectric energy-storage properties are crucial for polymer-based capacitors for harsh environment applications. However, biaxially oriented polypropylene (BOPP), a state-of-the-art commercial capacitor dielectric, can work only below 105 °C. Here, we present a versatile method to...

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Bibliographic Details
Published in:ACS applied energy materials 2022-03, Vol.5 (3), p.3119-3128
Main Authors: Bao, Zhiwei, Du, Xinzhe, Ding, Song, Chen, Jiahao, Dai, Zhizhan, Liu, Chuanchuan, Wang, Yuchen, Yin, Yuewei, Li, Xiaoguang
Format: Article
Language:English
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Summary:High-temperature dielectric energy-storage properties are crucial for polymer-based capacitors for harsh environment applications. However, biaxially oriented polypropylene (BOPP), a state-of-the-art commercial capacitor dielectric, can work only below 105 °C. Here, we present a versatile method to enhance its working temperature by depositing alumina (Al2O3) layers onto BOPP films via magnetron sputtering. Compared with a pure BOPP film, the sandwiched Al2O3/BOPP/Al2O3 structure shows a higher dielectric constant, a lower electrical conduction loss, stronger mechanical properties, higher thermal conductivity, and especially increased working temperature. As a result, the composite film delivers a high discharged energy density of 0.45 J/cm3 under 200 MV/m (the actual operating electric field in hybrid electric vehicles) at 125 °C. The discharged energy density and energy-storage efficiency (∼97.7%) are highly stable over 5000 cycles at 125 °C. This work provides an effective route to develop high-temperature polymer-based capacitors.
ISSN:2574-0962
2574-0962
DOI:10.1021/acsaem.1c03735