Imaging Voids and Defects Inside Li-Ion Cathode LiNi 0.6 Mn 0.2 Co 0.2 O 2 Single Crystals

• Published in: ACS applied materials & interfaces 2023-12, Vol.15 (51), p.59319-59328
• Main Authors: Martens, Isaac, Vanpeene, Victor, Vostrov, Nikita, Leake, Steven, Zatterin, Edoardo, Auvergniot, Jeremie, Drnec, Jakub, Richard, Marie-Ingrid, Villanova, Julie, Schulli, Tobias
• Format: Article
• Language: English
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.3c10509

Li-ion battery cathode active materials obtained from different sources or preparation methods often exhibit broadly divergent performance and stability despite no obvious differences in morphology, purity, and crystallinity. We show how state-of-the-art, commercial, nominally single crystalline LiNi Mn Co O (NMC-622) particles possess extensive internal nanostructure even in the pristine state. Scanning X-ray diffraction microscopy reveals the presence of interlayer strain gradients, and crystal bending is attributed to oxygen vacancies. Phase contrast X-ray nano-tomography reveals two different kinds of particles, welded/aggregated, and single crystal like, and emphasizes the intra- and interparticle heterogeneities from the nano- to the microscale. It also detects within the imaging resolution (100 nm) substantial quantities of nanovoids hidden inside the bulk of two-thirds of the overall studied particles (around 3000), with an average value of 12.5% per particle and a mean size of 148 nm. The powerful combination of both techniques helps prescreening and quantifying the defective nature of cathode material and thus anticipating their performance in electrode assembly/battery testing.