Efficient Upconverting Multiferroic Core@Shell Photocatalysts: Visible-to-Near-Infrared Photon Harvesting

We report the two-step synthesis of a core@shell nanohybrid material for visible-to-near-infrared (NIR) photocatalysis. The core is constituted of NaGdF4:Er3+, Yb3+ upconverting nanoparticles (UCNPs). A bismuth ferrite (BFO) shell is assembled around the UCNPs via a hydrothermal process. The photoca...

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Bibliographic Details
Published in:ACS applied materials & interfaces 2017-03, Vol.9 (9), p.8142-8150
Main Authors: Zhang, Jianming, Huang, Yue, Jin, Lei, Rosei, Federico, Vetrone, Fiorenzo, Claverie, Jerome P
Format: Article
Language:English
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Summary:We report the two-step synthesis of a core@shell nanohybrid material for visible-to-near-infrared (NIR) photocatalysis. The core is constituted of NaGdF4:Er3+, Yb3+ upconverting nanoparticles (UCNPs). A bismuth ferrite (BFO) shell is assembled around the UCNPs via a hydrothermal process. The photocatalytic degradation assays of methylene orange and 4-chlorophenol reveal that these core@shell nanostructures possess remarkably enhanced reaction activity under visible and NIR irradiation, compared to the BFO powder alone and the BFO-UCNP mixture. Photo-charge scavenger tests and fluorescent assays indicate that hydroxyl radicals play a pivotal role in the photodegradation mechanism. The enhanced photoactivity of the core@shell structure is attributed to the NIR radiation which is converted into visible light by UCNPs, and which is then captured by BFO via a nonradiative luminescence resonance energy transfer process. Therefore, this core@shell architecture optimizes solar energy use by efficiently harvesting visible and NIR photons.
ISSN:1944-8244
1944-8252
DOI:10.1021/acsami.7b00158