Trimodal Porous Hierarchical SSZ-13 Zeolite with Improved Catalytic Performance in the Methanol-to-Olefins Reaction

• Published in: ACS catalysis 2016-04, Vol.6 (4), p.2163-2177
• Main Authors: Zhu, Xiaochun, Hofmann, Jan P, Mezari, Brahim, Kosinov, Nikolay, Wu, Leilei, Qian, Qingyun, Weckhuysen, Bert M, Asahina, Shunsuke, Ruiz-Martínez, Javier, Hensen, Emiel J. M
• Format: Article
• Language: English
• ISSN: 2155-5435; 2155-5435
• DOI: 10.1021/acscatal.5b02480

Chabazite zeolites with trimodal porosity (native micropores of the CHA framework, an additional network of larger micropores of ∼0.5 nm, and mesopores) were synthesized by adding diquarternary ammonium-type surfactant C22–4–4 cations and fluoride anions in the synthesis of SSZ-13 zeolite. The hierarchical SSZ-13 zeolites are fully crystalline and exhibit similar acidity as bulk SSZ-13 zeolite. The increased diffusion rate in the hierarchical SSZ-13, proven by uptake experiments of bulky molecules and selective staining by thiophene oligomers, resulted in much slower catalyst deactivation in the methanol-to-olefins (MTO) reaction. Confocal fluorescent images of spent hierarchical SSZ-13 zeolites reveal homogeneous distribution of carbonaceous deposits, indicating that the micropore space has been completely utilized during the MTO reaction.