C–F/C–H Functionalization by Manganese(I) Catalysis: Expedient (Per)Fluoro-Allylations and Alkenylations

C–F/C–H functionalizations proved to be viable within a versatile manganese­(I) catalysis manifold. Thus, a wealth of fluorinated alkenes were employed in C–F/C–H functionalizations through facile C–H activation. The robust nature of the manganese­(I) catalysis regime was among others reflected by t...

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Bibliographic Details
Published in:ACS catalysis 2017-06, Vol.7 (6), p.4209-4213
Main Authors: Zell, Daniel, Dhawa, Uttam, Müller, Valentin, Bursch, Markus, Grimme, Stefan, Ackermann, Lutz
Format: Article
Language:English
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Summary:C–F/C–H functionalizations proved to be viable within a versatile manganese­(I) catalysis manifold. Thus, a wealth of fluorinated alkenes were employed in C–F/C–H functionalizations through facile C–H activation. The robust nature of the manganese­(I) catalysis regime was among others reflected by the first C–F/C–H activation with perfluoroalkenes as well as racemization-free C–H functionalizations on imines, amino acids, and peptides.
ISSN:2155-5435
2155-5435
DOI:10.1021/acscatal.7b01208