Easy-Iron Fabrics from Polysaccharide Shape Memory Fiber

• Published in: ACS sustainable chemistry & engineering 2024-07, Vol.12 (30), p.11435-11443
• Main Authors: Zhu, Kunkun, Yuan, Jingjing, Zhu, Xinhai, Li, Zuhuan, Ali, Shafqat, Zhang, Jinming, Shi, Shuo, Hu, Jinlian, Li, Yanan, Wang, Jinfeng, Zhang, Jun, Xu, Weilin
• Format: Article
• Language: English
• ISSN: 2168-0485; 2168-0485
• DOI: 10.1021/acssuschemeng.4c04765

Cellulose fabrics easily form wrinkles and need ironing treatment to maintain a flat appearance. However, burns and fire accidents caused by ironing clothes have been reported from time to time, as the recommended ironing temperature for cotton fabric is around 180 °C. Herein, an agarose/cellulose composite fiber with easy ironing was successfully prepared via a wet-spinning method by dissolving both agarose and cellulose in a specifically chosen mixed alkali/urea aqueous solution. The composite fiber exhibited superior mechanical properties, with a tensile strength of 164 MPa. Shape memory responses under the influence of water and heat stimulations indicated that the shape fixation ratios were 97–99 and 75–97%, respectively, and the shape recovery ratios were 80–92 and 67–94%, respectively. The composite fiber fabrics have shorter ironing times (2 s) and lower ironing temperatures (92 °C) compared with the regenerated cellulose fiber fabric. Furthermore, the composite fiber showed good dyeability, robust thermal and chemical stability, and a moderate level of biodegradability, capable of complete biodegradation in natural soil within 108 days. This work provided an avenue for fabricating hydrothermal-responsive shape memory fibers that have great potential application in easy ironing garments.