Natural Deep Eutectic Solvent-Catalyzed Selenocyanation of Activated Alkynes via an Intermolecular H‑Bonding Activation Process

By employing cheap and biodegradable natural deep eutectic solvent as the catalyst and reaction media, the selective selenocyanation of activated alkynes via an intermolecular H-bonding activation pathway has been achieved, which allows for the efficient construction of various Z-vinyl selenolates.

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Bibliographic Details
Published in:ACS sustainable chemistry & engineering 2019-01, Vol.7 (2), p.2169-2175
Main Authors: Wu, Chao, Xiao, Hai-Jing, Wang, Shu-Wen, Tang, Man-Sheng, Tang, Zi-Long, Xia, Wen, Li, Wen-Feng, Cao, Zhong, He, Wei-Min
Format: Article
Language:English
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Summary:By employing cheap and biodegradable natural deep eutectic solvent as the catalyst and reaction media, the selective selenocyanation of activated alkynes via an intermolecular H-bonding activation pathway has been achieved, which allows for the efficient construction of various Z-vinyl selenolates.
ISSN:2168-0485
2168-0485
DOI:10.1021/acssuschemeng.8b04877